Identification of radiolytic products of [C(4)mim][NTf2] and their effects on the Sr2+ extraction
Ao, YY; Peng, J; 袁立永;Yuan, LY; Cui, ZP; Li, C; Li, JQ; Zhai, ML
刊名DALTON TRANSACTIONS
2013
卷号42期号:12页码:4299-4305
学科分类Chemistry
DOI10.1039/c2dt32418k
英文摘要The trace water-soluble radiolytic products of neat 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)-imide ([C(4)mim][NTf2]) were identified by analysing water-washed samples of.-ray irradiated ionic liquids. CF3SO2OH, CF3SOOH, CF3SO2NH2, HF and H2SO3 were confirmed as main radiolytic products of [C(4)mim][NTf2], and the total radiation chemical yields of the water-soluble radiolytic products (0.35 mu mol J(-1)) and that of hydrogen ions (0.46 +/- 0.02 mu mol J(-1)) were determined by using ion chromatography and neutralization titration, respectively. It was found that the water-soluble radiolytic products of [C(4)mim][NTf2] greatly reduced the extraction efficiency of Sr2+ from water to irradiated [C(4)mim][NTf2], while the waterinsoluble radiolytic products of [C(4)mim][NTf2] had a slight influence on the Sr2+ extraction.
收录类别SCI
WOS记录号WOS:000315351800026
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被引频次:16[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/224250
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
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Ao, YY,Peng, J,袁立永;Yuan, LY,et al. Identification of radiolytic products of [C(4)mim][NTf2] and their effects on the Sr2+ extraction[J]. DALTON TRANSACTIONS,2013,42(12):4299-4305.
APA Ao, YY.,Peng, J.,袁立永;Yuan, LY.,Cui, ZP.,Li, C.,...&Zhai, ML.(2013).Identification of radiolytic products of [C(4)mim][NTf2] and their effects on the Sr2+ extraction.DALTON TRANSACTIONS,42(12),4299-4305.
MLA Ao, YY,et al."Identification of radiolytic products of [C(4)mim][NTf2] and their effects on the Sr2+ extraction".DALTON TRANSACTIONS 42.12(2013):4299-4305.
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