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Solvent Extraction of Cesium with a New Compound Calix[4]arene-bis[(4-methyl-1,2-phenylene)-crown-6]
Zhang, AY; Dai, Y; Xu, L; 柴之芳; Chai, ZF
刊名JOURNAL OF CHEMICAL AND ENGINEERING DATA
2013
卷号58期号:11页码:3275-3281
学科分类Chemistry; Engineering
DOI10.1021/je400735z
英文摘要A new macrocyclic calix[4]arene-bis[(4-methyl-1,2-phenylene)-crown-6] (CalixBisMePhC) was synthesized. An extraction study of Cs(I), Na(I), K(I), Rb(I), Sr(II), Ba(II), Pd(II), and Ru(III) with CalixBisMePhC/CHCl3 was investigated by examining the effects of contact time, HNO3 concentration, and temperature. The results showed that due to the effective molecular recognition, CalixBisMePhC/CHCl3 had excellent extraction ability and high selectivity for Cs(I) over the tested metals except Rb(I). The maximum distribution ratio for Cs(I) was found at the HNO3 concentration of 4.4 mol.kg(-1). The composition of the extracted species of Cs(I) was determined to be CsNO3 center dot 0.5CalixBisMePhC center dot 0.5HNO(3) by a slope method. Some valuable parameters for the Cs(I) extraction were obtained. The results demonstrated that the CalixBisMePhC/CHCl3 extraction system is promising to partition Cs(I) from highly level liquid waste.
收录类别SCI
WOS记录号WOS:000327110800051
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被引频次:8[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/224229
专题院士_期刊论文
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GB/T 7714
Zhang, AY,Dai, Y,Xu, L,et al. Solvent Extraction of Cesium with a New Compound Calix[4]arene-bis[(4-methyl-1,2-phenylene)-crown-6][J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA,2013,58(11):3275-3281.
APA Zhang, AY,Dai, Y,Xu, L,&柴之芳; Chai, ZF.(2013).Solvent Extraction of Cesium with a New Compound Calix[4]arene-bis[(4-methyl-1,2-phenylene)-crown-6].JOURNAL OF CHEMICAL AND ENGINEERING DATA,58(11),3275-3281.
MLA Zhang, AY,et al."Solvent Extraction of Cesium with a New Compound Calix[4]arene-bis[(4-methyl-1,2-phenylene)-crown-6]".JOURNAL OF CHEMICAL AND ENGINEERING DATA 58.11(2013):3275-3281.
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