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Structure of Clusters and Formation of Amorphous Calcium Phosphate and Hydroxyapatite: From the Perspective of Coordination Chemistry
Du, LW; Bian, S; Gou, BD; Jiang, Y; Huang, J; Gao, YX; Zhao, YD; Wen, W; Zhang, TL; Wang, K;高愈希; Zhao YD(赵屹东)
2013
发表期刊CRYSTAL GROWTH & DESIGN
卷号13期号:7页码:3103-3109
摘要Amorphous calcium phosphate often forms as a precursor phase in a solution at sufficiently high supersaturation and pH, and then transforms to the thermodynamically stable hydroxyapatite. The chemical composition, structure, and property of the amorphous phase are dependent on the structure of its composing clusters. Based on the results from the measurements of in situ Ca K-edge X-ray near-edge structure and ex situ X-ray diffraction, as well as the concomitant pH change in the reaction process, here we propose an improved model for the structure of "Posner's cluster" and identify the three types of reactions that lead to the formation of amorphous calcium phosphate and its subsequent transition to crystalline hydroxyapatite.
学科领域Chemistry; Crystallography; Materials Science
DOI10.1021/cg400498j
收录类别SCI
WOS记录号WOS:000321542900047
引用统计
被引频次:26[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/224223
专题多学科研究中心
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GB/T 7714
Du, LW,Bian, S,Gou, BD,et al. Structure of Clusters and Formation of Amorphous Calcium Phosphate and Hydroxyapatite: From the Perspective of Coordination Chemistry[J]. CRYSTAL GROWTH & DESIGN,2013,13(7):3103-3109.
APA Du, LW.,Bian, S.,Gou, BD.,Jiang, Y.,Huang, J.,...&赵屹东.(2013).Structure of Clusters and Formation of Amorphous Calcium Phosphate and Hydroxyapatite: From the Perspective of Coordination Chemistry.CRYSTAL GROWTH & DESIGN,13(7),3103-3109.
MLA Du, LW,et al."Structure of Clusters and Formation of Amorphous Calcium Phosphate and Hydroxyapatite: From the Perspective of Coordination Chemistry".CRYSTAL GROWTH & DESIGN 13.7(2013):3103-3109.
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