Structure of Clusters and Formation of Amorphous Calcium Phosphate and Hydroxyapatite: From the Perspective of Coordination Chemistry
Du, LW; Bian, S; Gou, BD; Jiang, Y; Huang, J; Gao, YX; Zhao, YD; Wen, W; Zhang, TL; Wang, K;高愈希; Zhao YD(赵屹东)
刊名CRYSTAL GROWTH & DESIGN
2013
卷号13期号:7页码:3103-3109
学科分类Chemistry; Crystallography; Materials Science
DOI10.1021/cg400498j
英文摘要Amorphous calcium phosphate often forms as a precursor phase in a solution at sufficiently high supersaturation and pH, and then transforms to the thermodynamically stable hydroxyapatite. The chemical composition, structure, and property of the amorphous phase are dependent on the structure of its composing clusters. Based on the results from the measurements of in situ Ca K-edge X-ray near-edge structure and ex situ X-ray diffraction, as well as the concomitant pH change in the reaction process, here we propose an improved model for the structure of "Posner's cluster" and identify the three types of reactions that lead to the formation of amorphous calcium phosphate and its subsequent transition to crystalline hydroxyapatite.
收录类别SCI
WOS记录号WOS:000321542900047
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被引频次:22[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/224223
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
中国科学院高能物理研究所_多学科研究中心
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Du, LW,Bian, S,Gou, BD,et al. Structure of Clusters and Formation of Amorphous Calcium Phosphate and Hydroxyapatite: From the Perspective of Coordination Chemistry[J]. CRYSTAL GROWTH & DESIGN,2013,13(7):3103-3109.
APA Du, LW.,Bian, S.,Gou, BD.,Jiang, Y.,Huang, J.,...&赵屹东.(2013).Structure of Clusters and Formation of Amorphous Calcium Phosphate and Hydroxyapatite: From the Perspective of Coordination Chemistry.CRYSTAL GROWTH & DESIGN,13(7),3103-3109.
MLA Du, LW,et al."Structure of Clusters and Formation of Amorphous Calcium Phosphate and Hydroxyapatite: From the Perspective of Coordination Chemistry".CRYSTAL GROWTH & DESIGN 13.7(2013):3103-3109.
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