Synthesis, Crystal Structure and Hydrogenation Catalysis of a CF3-BINAP(O)-Rh-COD Complex
Yang HF(杨红芬); Lu W(卢伟); 刘蕾(多); 刘宇(多); Wu HC(吴海臣); Yang, HF; Lu, W; Liu, L; Liu, Y; Wu, HC
刊名CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
2012
卷号31期号:11页码:1669-1675
关键词BINAP(O) ligand rhodium complex crystal structure asymmetric hydrogenation
学科分类Chemistry; Crystallography
英文摘要The complex [(CF3-BINAP(O))Rh(COD)][ClO4]center dot Et2O (2, CF3-BINAP(O) = 2-{bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-2'-{bis[3,5-bis(trifluoromethyl)phenyl]phosphinyl}-1,1'-binaphthyl, COD = 1,5-cyclooctadiene) was obtained directly from the reaction of CF3-BINAP(O) ligand with [Rh(COD)][ClO4]. Complex 2 has been characterized by single-crystal X-ray diffraction. The crystal adopts space group P2(1)/n with a = 19.0727(4), b = 15.6275(4), c = 22.3039(6) angstrom, beta = 112.3570(10)degrees, V = 6148.2(3) angstrom(3), Z = 4, D-c = 1.693 g/cm(3), F(000) = 3144, mu(MoK alpha) = 0.500 mm(-1), the final R = 0.0947 and wR = 0.2501. Structural studies reveal that Rh(I) is coordinated by one oxygen and one phosphorus in the same ligand. Asymmetric hydrogenation of acetamidocinnamic acid with compound 2 was also evaluated.
收录类别SCI
WOS记录号WOS:000311923500022
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文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/224161
专题中国科学院高能物理研究所_多学科研究中心_期刊论文
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Yang HF,Lu W,Liu L,et al. Synthesis, Crystal Structure and Hydrogenation Catalysis of a CF3-BINAP(O)-Rh-COD Complex[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2012,31(11):1669-1675.
APA 杨红芬.,卢伟.,刘蕾.,刘宇.,吴海臣.,...&Wu, HC.(2012).Synthesis, Crystal Structure and Hydrogenation Catalysis of a CF3-BINAP(O)-Rh-COD Complex.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,31(11),1669-1675.
MLA 杨红芬,et al."Synthesis, Crystal Structure and Hydrogenation Catalysis of a CF3-BINAP(O)-Rh-COD Complex".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 31.11(2012):1669-1675.
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