IHEP OpenIR  > 院士
Preparation of a Macroporous Silica-Based Multidentate Soft-Ligand Material and its Application in the Adsorption of Palladium and the Others
Zhang, AY; Jiang, JL;  Chai ZF(柴之芳);   Chai, ZF
2013
发表期刊SEPARATION SCIENCE AND TECHNOLOGY
卷号48期号:10页码:1500-1509
摘要To separate Pd(II), a macroporous silica-based soft-ligand 2,6-bis(5,6-di(iso-butyl)-1,2,4-triazine-3-yl)pyridine (BDIBTP) material, BDIBTP/SiO2-P, was synthesized by vacuum treatment. It was a multidentate chelating composite prepared by impregnation and immobilization of BDIBTP and 1-octanol molecules into the pores of the macroporous SiO2-P particles with a mean diameter of 50 mu m. 1-Octanol was used to modify BDIBTP through intermolecular interaction force. The adsorption of some typical fission products Zr(IV), Pd(II), La(III), Y(III), Ru(III), Rh(III), and Mo(VI) contained in highly active liquid waste (HLW) onto the BDIBTP/ SiO2-P materials was investigated. It was carried out by examining the effects of contact time and the concentration of HNO3 in the range of 0.3M7.0M. BDIBTP/SiO2-P showed excellent adsorption ability and high selectivity for Pd(II) over all of the tested metals. It was ascribed to the effective complexation of Pd(II) with BDIBTP/SiO2-P. Consideration of the complexation of BDIBTP for minor actinides MAs(III), the possibility and feasibility of effective partitioning of Pd(II) and MAs(III) simultaneously from a simulated HLW were discussed. A new concept process entitled MPS for the MA(III) and Pd(II) Separation has been proposed.
关键词adsorption highly active liquid waste palladium silica-pyridine material soft ligand synthesis
学科领域Chemistry; Engineering
DOI10.1080/01496395.2012.742108
收录类别SCI
WOS记录号WOS:000319040500009
引用统计
被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/224145
专题院士
推荐引用方式
GB/T 7714
Zhang, AY,Jiang, JL;柴之芳; Chai, ZF. Preparation of a Macroporous Silica-Based Multidentate Soft-Ligand Material and its Application in the Adsorption of Palladium and the Others[J]. SEPARATION SCIENCE AND TECHNOLOGY,2013,48(10):1500-1509.
APA Zhang, AY,&Jiang, JL;柴之芳; Chai, ZF.(2013).Preparation of a Macroporous Silica-Based Multidentate Soft-Ligand Material and its Application in the Adsorption of Palladium and the Others.SEPARATION SCIENCE AND TECHNOLOGY,48(10),1500-1509.
MLA Zhang, AY,et al."Preparation of a Macroporous Silica-Based Multidentate Soft-Ligand Material and its Application in the Adsorption of Palladium and the Others".SEPARATION SCIENCE AND TECHNOLOGY 48.10(2013):1500-1509.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
6599.pdf(730KB)期刊论文作者接受稿限制开放CC BY-NC-SA请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Zhang, AY]的文章
[Jiang, JL;柴之芳; Chai, ZF]的文章
百度学术
百度学术中相似的文章
[Zhang, AY]的文章
[Jiang, JL;柴之芳; Chai, ZF]的文章
必应学术
必应学术中相似的文章
[Zhang, AY]的文章
[Jiang, JL;柴之芳; Chai, ZF]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。