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High pressure structural study of beta-Ti3O5: X-ray diffraction and Raman spectroscopy
Wu, Y; Zhang, Q; Wu, X; Qin, S; Liu, J;刘景
2012
发表期刊JOURNAL OF SOLID STATE CHEMISTRY
卷号192页码:356-359
摘要The structural stability of beta-Ti3O5 (C2/m) has been investigated by X-ray diffraction and Raman spectroscopy with diamond anvil cells. beta-Ti3O5 is stable up to about 26 GPa at room temperature. Isothermal pressure-volume relationship of beta-Ti3O5 is well presented by the third-order Birch-Murnaghan equation of state with V-0=348.6(8) angstrom(3) and B-0=216(9) GPa. Axial compressibility presents obvious anisotropy. The a-axis and c-axis are more compressible than b-axis due to the different crystal structure arrangement of beta-Ti3O5 along b-axis and perpendicular to b-axis direction. The Gruneisen parameters of thirteen observed Raman modes are 0.79-1.74, whose mean is 1.32. Crown Copyright (C) 2012 Published by Elsevier Inc. All rights reserved.
关键词beta-Ti3O5 High pressure Structural stability Equation of state X-ray diffraction Raman spectroscopy
学科领域Chemistry
DOI10.1016/j.jssc.2012.04.036
收录类别SCI
WOS记录号WOS:000307028300052
引用统计
被引频次:11[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/223951
专题多学科研究中心
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GB/T 7714
Wu, Y,Zhang, Q,Wu, X,et al. High pressure structural study of beta-Ti3O5: X-ray diffraction and Raman spectroscopy[J]. JOURNAL OF SOLID STATE CHEMISTRY,2012,192:356-359.
APA Wu, Y,Zhang, Q,Wu, X,Qin, S,&Liu, J;刘景.(2012).High pressure structural study of beta-Ti3O5: X-ray diffraction and Raman spectroscopy.JOURNAL OF SOLID STATE CHEMISTRY,192,356-359.
MLA Wu, Y,et al."High pressure structural study of beta-Ti3O5: X-ray diffraction and Raman spectroscopy".JOURNAL OF SOLID STATE CHEMISTRY 192(2012):356-359.
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