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Structural Characterization and Luminescence Properties of a Triphosphine-Stabilized Ag16Cu9 Heterometallic Alkynyl Cluster
Chen, ZH; Zhang, LY; 陈忠宁;Chen, ZN
2012
发表期刊ORGANOMETALLICS
卷号31期号:1页码:256-260
摘要A triphosphine-stabilized Ag16Cu9 heterometallic alkynyl cluster complex was prepared by the reaction of polymeric silver(I) (4-tert-butylpheny1)acetylide with a copper(I) dpepp (dpepp = bis(2-(diphenylphosphino)ethyl)phenylphosphine) complex and characterized by X-ray crystallography. This Ag16Cu9 heterometallic alkynyl complex exhibits an unprecedented structural topology stabilized by three auxiliary triphosphine ligands. The (4-tert-butylphenypacetylide exhibits five types of asymmetric bonding modes, including mu-eta(1), mu-eta(1)(sigma):eta(2)(pi), mu(3)-eta(1), mu(3)-eta(1)(sigma):eta(1)(sigma):eta(2)(pi), and eta(1)-mu(4). This Ag16Cu9 complex exhibits visible to near-infrared luminescence in both fluid CH2Cl2 solution and the solid state.
学科领域Chemistry
DOI10.1021/om200836k
收录类别SCI
WOS记录号WOS:000298897700029
引用统计
被引频次:22[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.ihep.ac.cn/handle/311005/223913
专题多学科研究中心
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GB/T 7714
Chen, ZH,Zhang, LY,陈忠宁;Chen, ZN. Structural Characterization and Luminescence Properties of a Triphosphine-Stabilized Ag16Cu9 Heterometallic Alkynyl Cluster[J]. ORGANOMETALLICS,2012,31(1):256-260.
APA Chen, ZH,Zhang, LY,&陈忠宁;Chen, ZN.(2012).Structural Characterization and Luminescence Properties of a Triphosphine-Stabilized Ag16Cu9 Heterometallic Alkynyl Cluster.ORGANOMETALLICS,31(1),256-260.
MLA Chen, ZH,et al."Structural Characterization and Luminescence Properties of a Triphosphine-Stabilized Ag16Cu9 Heterometallic Alkynyl Cluster".ORGANOMETALLICS 31.1(2012):256-260.
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